One-pot synthesis of xanthene derivatives catalyzed by Fe(III) tetranitrophthalocyanine immobilized on activated carbon


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Abstract

Xanthene derivatives were synthesized by a multicomponent one-pot reaction of aromatic aldehydes, β-naphthol, and 5,5-dimethylcyclohexane-1,3-dione or 1,3-cyclohexanedione upon efficient and eco-friendly catalysis of Fe(III) tetranitrophthalocyanine immobilized on activated carbon in ethanol. The method tolerated a variety of functional groups and the process was carried out under mild conditions to give high yield of products (85–91%) in 30 min. The catalyst can be recycled without any loss in catalytic activity.

About the authors

H. Huang

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry and Materials Science

Author for correspondence.
Email: xdny917@163.com
China, Xi’an, 710127

Y. Yao

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry and Materials Science

Email: xdny917@163.com
China, Xi’an, 710127

Q. Lin

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry and Materials Science

Email: xdny917@163.com
China, Xi’an, 710127

J. Zhao

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry and Materials Science

Email: xdny917@163.com
China, Xi’an, 710127

C. Hua

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry and Materials Science

Email: xdny917@163.com
China, Xi’an, 710127

X. Gou

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry and Materials Science

Email: xdny917@163.com
China, Xi’an, 710127


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