The effect of functional substitution on thermal stability of pyridinylporphyrins under argon atmosphere

N. M. Berezina; Do Ngoc Minh; Yu. I. Tikhonova; N. N. Tumanova; S. S. Guseinov; M. I. Bazanov; M. B. Berezin; A. V. Glazunov; A. S. Semeikin

doi:10.1134/S1070363216040137

The effect of functional substitution on thermal stability of pyridinylporphyrins under argon atmosphere

Authors: Berezina N.M.¹, Minh D.N.¹, Tikhonova Y.I.¹, Tumanova N.N.¹, Guseinov S.S.², Bazanov M.I.¹, Berezin M.B.², Glazunov A.V.¹, Semeikin A.S.¹
Affiliations:
1. Ivanovo State University of Chemistry and Technology
2. G.A. Krestov Institute of Solutions Chemistry
Issue: Vol 86, No 4 (2016)
Pages: 835-839
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/214620
DOI: https://doi.org/10.1134/S1070363216040137
ID: 214620

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Abstract

The data on thermal stability under argon atmosphere of a series of porphyrin ligands containing meso- and β-positioned electron-donor (Me, Et, or Ph) groups as well as electron-acceptor pyridinyl substituents differing in the heteroatom location are presented. Thermogravimetric analysis and electron absorption spectroscopy studies have shown that pyridinylporphyrins are thermally stable at heating to 360–500°С depending on the functional substitution in the molecule.