1-chloroacetyloxindole(isatin) in reactions with some N-nucleophiles. Unexpetedly easy cleavage of chloroacetyl group
- Authors: Bogdanov A.V.1, Kutuzova T.A.1, Krivolapov D.B.1, Dobrynin A.B.1, Mironov V.F.1
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Affiliations:
- Arbuzov Institute of Organic and Physical Chemistry
- Issue: Vol 86, No 3 (2016)
- Pages: 539-543
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214172
- DOI: https://doi.org/10.1134/S1070363216030087
- ID: 214172
Cite item
Abstract
Reactions of 1-chloroacetyloxindole and 1-chloroacetylisatin with some secondary amines, Girard’s reagent T and thiourea were studied. All investigated reactions proceeded via cleavage of the acyl group to form 3-substituted isatin or oxindole derivatives.
Keywords
About the authors
A. V. Bogdanov
Arbuzov Institute of Organic and Physical Chemistry
Author for correspondence.
Email: abogdanov@inbox.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
T. A. Kutuzova
Arbuzov Institute of Organic and Physical Chemistry
Email: abogdanov@inbox.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
D. B. Krivolapov
Arbuzov Institute of Organic and Physical Chemistry
Email: abogdanov@inbox.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
A. B. Dobrynin
Arbuzov Institute of Organic and Physical Chemistry
Email: abogdanov@inbox.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
V. F. Mironov
Arbuzov Institute of Organic and Physical Chemistry
Email: abogdanov@inbox.ru
Russian Federation, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088