Email this article Cycloaddition and chlorotropic transformations in reactions of dichloromethylenetrifluoroacetamide with phosphites
- Authors: Kolotilo N.V.1, Onys’ko P.P.1
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Affiliations:
- Institute of Organic Chemistry
- Issue: Vol 86, No 3 (2016)
- Pages: 534-538
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214167
- DOI: https://doi.org/10.1134/S1070363216030075
- ID: 214167
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Abstract
Reactions of dichlormethylenetrifluoroacetamide with triphenyl phosphite, diethylchlorophosphite (o-phenylene)diethylamidophosphite, (o-phenylene)chlorphosphite, and 2-fluoro-3-isopropyl-5-tert-butyl-1,3,2-oxazaphospholine proceeded as cheletropic [4+1]-cycloaddition. The formed λ5-1,4,2-oxazaphospholines underwent 1,3-migration of the chlorine atom in C=N–C cyclic triad.
About the authors
N. V. Kolotilo
Institute of Organic Chemistry
Email: onysko_@ukr.net
Ukraine, ul. Murmanskaya 5, Kiev, 02094
P. P. Onys’ko
Institute of Organic Chemistry
Author for correspondence.
Email: onysko_@ukr.net
Ukraine, ul. Murmanskaya 5, Kiev, 02094
