N-alkyl-2-halo- and 2,2-dihaloaldimines in the Pudovik reaction
- Authors: Gazizov M.B.1, Khairullin R.A.1, Perina A.I.1, Minnikhanova A.A.1, Aksenov N.G.1, Gnezdilov O.I.1, Il’yasov A.V.1, Khayarov K.R.1
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Affiliations:
- Kazan Research Institute of Technology
- Issue: Vol 86, No 3 (2016)
- Pages: 499-507
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214140
- DOI: https://doi.org/10.1134/S1070363216030014
- ID: 214140
Cite item
Abstract
The use of N-alkyl-2-haloaldimines in the imine version of the Pudovik reaction, namely, in the reaction of imines with acid esters of phosphorus acids, much extended the synthetic potential of this reaction due to the fact that the primary addition and protonation product, having quite a mobile single hylogen atom, can undergo both spontaneous transformations and transformations involving other reagents. The reduction of the С–Hlg bond in N-alkyl-2-halo- and -2,2-dihaloaldiminium salts with О,О-dialkyl phosphorodithioic acids was observed for the first time.
About the authors
M. B. Gazizov
Kazan Research Institute of Technology
Author for correspondence.
Email: mukattisg@mail.ru
Russian Federation, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
R. A. Khairullin
Kazan Research Institute of Technology
Email: mukattisg@mail.ru
Russian Federation, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
A. I. Perina
Kazan Research Institute of Technology
Email: mukattisg@mail.ru
Russian Federation, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
A. A. Minnikhanova
Kazan Research Institute of Technology
Email: mukattisg@mail.ru
Russian Federation, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
N. G. Aksenov
Kazan Research Institute of Technology
Email: mukattisg@mail.ru
Russian Federation, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
O. I. Gnezdilov
Kazan Research Institute of Technology
Email: mukattisg@mail.ru
Russian Federation, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
A. V. Il’yasov
Kazan Research Institute of Technology
Email: mukattisg@mail.ru
Russian Federation, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
Kh. R. Khayarov
Kazan Research Institute of Technology
Email: mukattisg@mail.ru
Russian Federation, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
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