Synthesis of per-6-О-(tert-butyl)(diphenyl)silyl-β-cyclodextrin


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Abstract

Per-6-O-(tert-butyl)(diphenyl)silyl-β-silylcyclodextrin has been obtained regioselectively via the reaction with tert-butyldiphenylchlorosilane. Further treatment of the product with chlorosilanes has led to the corresponding derivatives of β-cyclodextrin with mixed silyl groups at the primary hydroxyl groups.

About the authors

G. I. Kurochkina

Institute of Biology and Chemistry

Email: iilevina@rambler.ru
Russian Federation, Nesvizhskii per. 3, Moscow, 119021

A. V. Popkov

Institute of Biology and Chemistry

Email: iilevina@rambler.ru
Russian Federation, Nesvizhskii per. 3, Moscow, 119021

I. I. Levina

N.M. Emanuel Institute of Biochemical Physics

Author for correspondence.
Email: iilevina@rambler.ru
Russian Federation, ul. Kosygina 4, Moscow, 119334

M. K. Grachev

Institute of Biology and Chemistry

Email: iilevina@rambler.ru
Russian Federation, Nesvizhskii per. 3, Moscow, 119021

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