Synthesis and properties of Sc- and Mg-doped bismuth titanates with the pyrochlore structure


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Abstract

Scandium(Magnesium)-containing bismuth titanates with the pyrochlore structure have been synthesized for the first time. Their homogeneity range has been determined by means of X-ray diffraction analysis and scanning electronic microscopy. Scandium and magnesium distribution over the cationic positions has been studied. Electrophysical properties of single-phase compounds have been studied. The total conductivity of the compounds is a function of magnesium (scandium) and bismuth concentrations.

About the authors

A. G. Krasnov

Institute of Chemistry, Komi Scientific Center, Ural Branch

Author for correspondence.
Email: alexey-krasnov@rambler.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982

M. M. Piskaikina

Ukhta State Technical University

Email: alexey-krasnov@rambler.ru
Russian Federation, Ukhta

I. V. Piir

Institute of Chemistry, Komi Scientific Center, Ural Branch

Email: alexey-krasnov@rambler.ru
Russian Federation, ul. Pervomaiskaya 48, Syktyvkar, 167982


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