Functionalized polynorbornenes with organosilicon groups in the side chains. Synthesis and photophysical properties

Е. О. Platonova; Т. А. Kovylina; Е. V. Baranov; А. V. Arapova; L. N. Bochkarev

doi:10.1134/S1070363216010205

Functionalized polynorbornenes with organosilicon groups in the side chains. Synthesis and photophysical properties

Authors: Platonova Е.О.¹, Kovylina Т.А.¹, Baranov Е.V.¹^,2, Arapova А.V.¹, Bochkarev L.N.¹^,2
Affiliations:
1. G.A. Razuvaev Institute of Organometallic Chemistry
2. N.I. Lobachevskii Nizhny Novgorod State University
Issue: Vol 86, No 1 (2016)
Pages: 116-124
Section: Article
URL: https://journals.rcsi.science/1070-3632/article/view/213466
DOI: https://doi.org/10.1134/S1070363216010205
ID: 213466

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Abstract

Using the method of metathesis polymerization carbon-chain homopolymers containing triрhenylsilyl, tritolylsilyl and trithienylsilyl groups in the side chains, as well as their copolymers with additional carbazole-containing units have been synthesized. Photophysical properties of the obtained compounds were investigated. All polymer products show an intense photoluminescence in the blue region of the spectrum. The largest quantum yield (61.4%) was shown by the copolymer with triphenylsilyl and carbazole side groups.

Keywords

silicon-containing carbon-chain polymers, norbornene monomers, metathesis polymerization, photophysical properties

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Functionalized polynorbornenes with organosilicon groups in the side chains. Synthesis and photophysical properties

Full Text

Abstract

Keywords

About the authors

Е. О. Platonova

Т. А. Kovylina

Е. V. Baranov

А. V. Arapova

L. N. Bochkarev

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