Complex formation of β-brominated tetraphenylporphyrins and metal exchange of their cadmium complexes with d-metal salts in dimethylformamide


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Abstract

Complex formation of zinc and copper(II) acetates with tetraphenylporphyrin, 2-bromo-5,10,15,20-tetraphenylporphyrin, 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin, and 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin in N,N-dimethylformamide has been studied. The rate constants determined in the study of the complex formation and the metal exchange reactions have been compared.

About the authors

O. V. Maltseva

Krestov Institute of Solutions Chemistry

Author for correspondence.
Email: ovt@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045

S. V. Zvezdina

Krestov Institute of Solutions Chemistry

Email: ovt@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045

N. V. Chizhova

Krestov Institute of Solutions Chemistry

Email: ovt@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045

N. Zh. Mamardashvili

Krestov Institute of Solutions Chemistry

Email: ovt@isc-ras.ru
Russian Federation, ul. Akademicheskaya 1, Ivanovo, 153045


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