Complex formation between derivatives of pyridine N-oxides and iron(III) nitrate in aqueous medium


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Abstract

Donor-acceptor complexes of derivatives of pyridine N-oxides with iron(III) nitrate have been studied. Their stability constants in water and in aqueous acetone have been determined. The complexes stability increases upon heating, at decreasing solvent polarity, and in the presence of the substituents in the N-oxide ring.

About the authors

A. V. Ryzhakov

Institute of Northern Water Problems, Karelian Research Centre

Author for correspondence.
Email: ryzhakov@nwpi.krc.karelia.ru
Russian Federation, pr. Aleksandra Nevskogo 50, Petrozavodsk, 185003

V. P. Andreev

Petrozavodsk State University

Email: ryzhakov@nwpi.krc.karelia.ru
Russian Federation, Petrozavodsk


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