Ferromagnetic Behavior of an Uncommon Trinuclearcopper(II) Coordination Polymer Based on Tartarate and 1,2-bis(4-Pyridyl)ethane Linker


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A new Cu(II) based metal-organic framework (MOF) having formula [Cu3(H2Tar)(Tar)-(H2O)(Bpa)] · 3H2O (I) (H4Tar = tartaric acid, Bpa = 1,2-bis(4-pyridyl)ethane) has been characterized by elemental analysis, FT-IR spectra, thermal analysis, and single-crystal X-ray diffraction (CIF file CCDC no. 1575136). In I, the Cu(II) center are connected by four symmetry-related tartrate ligands into a 2D layer encapsulating trinuclear cluster, which are further bridged by Bpa molecules into a 3D framework. Complex I exhibits strong ferromagnetic behavior between metal centers.

作者简介

J. Jin

Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology; West Anhui Health Vocational College

Email: jianqiangliu2010@126.com
中国, Anhui, 237012; Anhui, 237012

E. Zhou

Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology; West Anhui Health Vocational College

Email: jianqiangliu2010@126.com
中国, Anhui, 237012; Anhui, 237012

B. Li

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy

Email: jianqiangliu2010@126.com
中国, Dongguan, 523808

H. Zhong

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy

Email: jianqiangliu2010@126.com
中国, Dongguan, 523808

H. Zeng

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy

Email: jianqiangliu2010@126.com
中国, Dongguan, 523808

J. Zhang

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy

Email: jianqiangliu2010@126.com
中国, Dongguan, 523808

J. Liu

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy

编辑信件的主要联系方式.
Email: jianqiangliu2010@126.com
中国, Dongguan, 523808

M. Luo

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy

Email: jianqiangliu2010@126.com
中国, Dongguan, 523808

Y. Wang

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science

Email: jianqiangliu2010@126.com
中国, Xi’an, 710069

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