Ferromagnetic Behavior of an Uncommon Trinuclearcopper(II) Coordination Polymer Based on Tartarate and 1,2-bis(4-Pyridyl)ethane Linker


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Аннотация

A new Cu(II) based metal-organic framework (MOF) having formula [Cu3(H2Tar)(Tar)-(H2O)(Bpa)] · 3H2O (I) (H4Tar = tartaric acid, Bpa = 1,2-bis(4-pyridyl)ethane) has been characterized by elemental analysis, FT-IR spectra, thermal analysis, and single-crystal X-ray diffraction (CIF file CCDC no. 1575136). In I, the Cu(II) center are connected by four symmetry-related tartrate ligands into a 2D layer encapsulating trinuclear cluster, which are further bridged by Bpa molecules into a 3D framework. Complex I exhibits strong ferromagnetic behavior between metal centers.

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Авторлар туралы

J. Jin

Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology; West Anhui Health Vocational College

Email: jianqiangliu2010@126.com
ҚХР, Anhui, 237012; Anhui, 237012

E. Zhou

Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology; West Anhui Health Vocational College

Email: jianqiangliu2010@126.com
ҚХР, Anhui, 237012; Anhui, 237012

B. Li

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy

Email: jianqiangliu2010@126.com
ҚХР, Dongguan, 523808

H. Zhong

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy

Email: jianqiangliu2010@126.com
ҚХР, Dongguan, 523808

H. Zeng

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy

Email: jianqiangliu2010@126.com
ҚХР, Dongguan, 523808

J. Zhang

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy

Email: jianqiangliu2010@126.com
ҚХР, Dongguan, 523808

J. Liu

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy

Хат алмасуға жауапты Автор.
Email: jianqiangliu2010@126.com
ҚХР, Dongguan, 523808

M. Luo

Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy

Email: jianqiangliu2010@126.com
ҚХР, Dongguan, 523808

Y. Wang

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science

Email: jianqiangliu2010@126.com
ҚХР, Xi’an, 710069

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