Ferromagnetic Behavior of an Uncommon Trinuclearcopper(II) Coordination Polymer Based on Tartarate and 1,2-bis(4-Pyridyl)ethane Linker
- Авторы: Jin J.C.1,2, Zhou E.H.1,2, Li B.H.3, Zhong H.R.3, Zeng H.D.3, Zhang J.X.3, Liu J.Q.3, Luo M.M.3, Wang Y.Y.4
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Учреждения:
- Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology
- West Anhui Health Vocational College
- Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
- Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science
- Выпуск: Том 44, № 7 (2018)
- Страницы: 432-438
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214561
- DOI: https://doi.org/10.1134/S1070328418070072
- ID: 214561
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Аннотация
A new Cu(II) based metal-organic framework (MOF) having formula [Cu3(H2Tar)(Tar)-(H2O)(Bpa)] · 3H2O (I) (H4Tar = tartaric acid, Bpa = 1,2-bis(4-pyridyl)ethane) has been characterized by elemental analysis, FT-IR spectra, thermal analysis, and single-crystal X-ray diffraction (CIF file CCDC no. 1575136). In I, the Cu(II) center are connected by four symmetry-related tartrate ligands into a 2D layer encapsulating trinuclear cluster, which are further bridged by Bpa molecules into a 3D framework. Complex I exhibits strong ferromagnetic behavior between metal centers.
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Об авторах
J. Jin
Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology; West Anhui Health Vocational College
Email: jianqiangliu2010@126.com
Китай, Anhui, 237012; Anhui, 237012
E. Zhou
Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology; West Anhui Health Vocational College
Email: jianqiangliu2010@126.com
Китай, Anhui, 237012; Anhui, 237012
B. Li
Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
Email: jianqiangliu2010@126.com
Китай, Dongguan, 523808
H. Zhong
Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
Email: jianqiangliu2010@126.com
Китай, Dongguan, 523808
H. Zeng
Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
Email: jianqiangliu2010@126.com
Китай, Dongguan, 523808
J. Zhang
Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
Email: jianqiangliu2010@126.com
Китай, Dongguan, 523808
J. Liu
Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
Автор, ответственный за переписку.
Email: jianqiangliu2010@126.com
Китай, Dongguan, 523808
M. Luo
Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
Email: jianqiangliu2010@126.com
Китай, Dongguan, 523808
Y. Wang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science
Email: jianqiangliu2010@126.com
Китай, Xi’an, 710069
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