Email this article Ferromagnetic Behavior of an Uncommon Trinuclearcopper(II) Coordination Polymer Based on Tartarate and 1,2-bis(4-Pyridyl)ethane Linker
- Authors: Jin J.C.1,2, Zhou E.H.1,2, Li B.H.3, Zhong H.R.3, Zeng H.D.3, Zhang J.X.3, Liu J.Q.3, Luo M.M.3, Wang Y.Y.4
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Affiliations:
- Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology
- West Anhui Health Vocational College
- Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
- Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science
- Issue: Vol 44, No 7 (2018)
- Pages: 432-438
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214561
- DOI: https://doi.org/10.1134/S1070328418070072
- ID: 214561
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Abstract
A new Cu(II) based metal-organic framework (MOF) having formula [Cu3(H2Tar)(Tar)-(H2O)(Bpa)] · 3H2O (I) (H4Tar = tartaric acid, Bpa = 1,2-bis(4-pyridyl)ethane) has been characterized by elemental analysis, FT-IR spectra, thermal analysis, and single-crystal X-ray diffraction (CIF file CCDC no. 1575136). In I, the Cu(II) center are connected by four symmetry-related tartrate ligands into a 2D layer encapsulating trinuclear cluster, which are further bridged by Bpa molecules into a 3D framework. Complex I exhibits strong ferromagnetic behavior between metal centers.
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About the authors
J. C. Jin
Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology; West Anhui Health Vocational College
Email: jianqiangliu2010@126.com
China, Anhui, 237012; Anhui, 237012
E. H. Zhou
Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology; West Anhui Health Vocational College
Email: jianqiangliu2010@126.com
China, Anhui, 237012; Anhui, 237012
B. H. Li
Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
Email: jianqiangliu2010@126.com
China, Dongguan, 523808
H. R. Zhong
Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
Email: jianqiangliu2010@126.com
China, Dongguan, 523808
H. D. Zeng
Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
Email: jianqiangliu2010@126.com
China, Dongguan, 523808
J. X. Zhang
Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
Email: jianqiangliu2010@126.com
China, Dongguan, 523808
J. Q. Liu
Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
Author for correspondence.
Email: jianqiangliu2010@126.com
China, Dongguan, 523808
M. M. Luo
Dongguan Key Laboratory of Drug Design and Formulation Technology, Key Laboratory of Research and Development of New Medical Materials of Guangdong Medical University, School of Pharmacy
Email: jianqiangliu2010@126.com
China, Dongguan, 523808
Y. Y. Wang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science
Email: jianqiangliu2010@126.com
China, Xi’an, 710069
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