1-Chloro-1,3-dimethyl-1,3-diorganyl-3-(trimethylsilylamino)disiloxanes
- 作者: Basenko S.1, Soldatenko A.1
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隶属关系:
- A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- 期: 卷 66, 编号 6 (2017)
- 页面: 1074-1077
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240783
- DOI: https://doi.org/10.1007/s11172-017-1856-y
- ID: 240783
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详细
The main products of the reaction of 1,3-dichloro-1,3-dimethyl-1,3-diorganyldisiloxanes with hexamethyldisilazane (molar ratio 1 : 1, 20 °C) are the earlier unknown linear 1-chloro-1,3-dimethyl-1,3-diorganyl-3-(trimethylsilylamino)disiloxanes of the general formula ClMeRSiOSiMeRNHSiMe3 (1) (R = ClCH2 (a), Me (b), Vin (c), Ph (d)) obtained in up to 53—72% yield and 1,3-dimethyl-1,3-diorganyl-1,3-bis(trimethylsilylamino)disiloxanes of the general formula (Me3SiNH)MeRSiOSiMeR(NHSiMe3) (2a—d) (7—12% yield). Thermolysis of compounds 1a—d leads to the formation of cyclic silazaoxanes. A plausible scheme for their formation was suggested.
作者简介
S. Basenko
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
编辑信件的主要联系方式.
Email: sv_basenko@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033
A. Soldatenko
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: sv_basenko@irioch.irk.ru
俄罗斯联邦, 1 ul. Favorskogo, Irkutsk, 664033