1-Chloro-1,3-dimethyl-1,3-diorganyl-3-(trimethylsilylamino)disiloxanes
- Авторлар: Basenko S.1, Soldatenko A.1
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Мекемелер:
- A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- Шығарылым: Том 66, № 6 (2017)
- Беттер: 1074-1077
- Бөлім: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240783
- DOI: https://doi.org/10.1007/s11172-017-1856-y
- ID: 240783
Дәйексөз келтіру
Аннотация
The main products of the reaction of 1,3-dichloro-1,3-dimethyl-1,3-diorganyldisiloxanes with hexamethyldisilazane (molar ratio 1 : 1, 20 °C) are the earlier unknown linear 1-chloro-1,3-dimethyl-1,3-diorganyl-3-(trimethylsilylamino)disiloxanes of the general formula ClMeRSiOSiMeRNHSiMe3 (1) (R = ClCH2 (a), Me (b), Vin (c), Ph (d)) obtained in up to 53—72% yield and 1,3-dimethyl-1,3-diorganyl-1,3-bis(trimethylsilylamino)disiloxanes of the general formula (Me3SiNH)MeRSiOSiMeR(NHSiMe3) (2a—d) (7—12% yield). Thermolysis of compounds 1a—d leads to the formation of cyclic silazaoxanes. A plausible scheme for their formation was suggested.
Авторлар туралы
S. Basenko
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: sv_basenko@irioch.irk.ru
Ресей, 1 ul. Favorskogo, Irkutsk, 664033
A. Soldatenko
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: sv_basenko@irioch.irk.ru
Ресей, 1 ul. Favorskogo, Irkutsk, 664033