Enviar artigo por via de e-mail 1-Chloro-1,3-dimethyl-1,3-diorganyl-3-(trimethylsilylamino)disiloxanes
- Autores: Basenko S.1, Soldatenko A.1
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Afiliações:
- A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- Edição: Volume 66, Nº 6 (2017)
- Páginas: 1074-1077
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240783
- DOI: https://doi.org/10.1007/s11172-017-1856-y
- ID: 240783
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Resumo
The main products of the reaction of 1,3-dichloro-1,3-dimethyl-1,3-diorganyldisiloxanes with hexamethyldisilazane (molar ratio 1 : 1, 20 °C) are the earlier unknown linear 1-chloro-1,3-dimethyl-1,3-diorganyl-3-(trimethylsilylamino)disiloxanes of the general formula ClMeRSiOSiMeRNHSiMe3 (1) (R = ClCH2 (a), Me (b), Vin (c), Ph (d)) obtained in up to 53—72% yield and 1,3-dimethyl-1,3-diorganyl-1,3-bis(trimethylsilylamino)disiloxanes of the general formula (Me3SiNH)MeRSiOSiMeR(NHSiMe3) (2a—d) (7—12% yield). Thermolysis of compounds 1a—d leads to the formation of cyclic silazaoxanes. A plausible scheme for their formation was suggested.
Sobre autores
S. Basenko
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: sv_basenko@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
A. Soldatenko
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: sv_basenko@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
