Ferrocenecarboxylic acid and microwave-assisted synthesis of ferrocenoyl hydrazones
- 作者: Kulikov V.1,2, Nikulin R.1,2, Arkhipov D.1, Rodionov A.1, Babusenko E.2, Kovalenko L.2, Belousov Y.1
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隶属关系:
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- D. Mendeleev University of Chemical Technology of Russia
- 期: 卷 66, 编号 3 (2017)
- 页面: 537-544
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240274
- DOI: https://doi.org/10.1007/s11172-017-1768-x
- ID: 240274
如何引用文章
详细
A protocol to access ferrocenecarboxylic acid via carboxylation of ferrocene with carbon dioxide in the presence of aluminum chloride was elaborated. An efficient microwave-assisted synthesis of ferrocenoyl hydrazones by condensation of ferrocene carbohydrazide with carbonyl compounds was developed. Structures of the synthesized compounds were examined by NMR spectroscopy and mass spectrometry. Structures of N´-(4-chlorobenzylidene)ferrocenecarbohydrazide, N´-(4-methoxybenzylidene)ferrocenecarbohydrazide, and N´-(2-hydroxybenzylidene)ferrocenecarbohydrazide were determined by X-ray diffraction analysis. Synthesized compounds were found to have no toxicity against P. aeruginosa, E. coli, S. aureus, B. subtilis, M. rubrum, and C. albicans.
作者简介
V. Kulikov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; D. Mendeleev University of Chemical Technology of Russia
编辑信件的主要联系方式.
Email: kulikov_v_n@mail.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991; 9 Miusskaya pl., Moscow, 125047
R. Nikulin
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; D. Mendeleev University of Chemical Technology of Russia
Email: belur@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991; 9 Miusskaya pl., Moscow, 125047
D. Arkhipov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: belur@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
A. Rodionov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: belur@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
E. Babusenko
D. Mendeleev University of Chemical Technology of Russia
Email: belur@ineos.ac.ru
俄罗斯联邦, 9 Miusskaya pl., Moscow, 125047
L. Kovalenko
D. Mendeleev University of Chemical Technology of Russia
Email: belur@ineos.ac.ru
俄罗斯联邦, 9 Miusskaya pl., Moscow, 125047
Yu. Belousov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: belur@ineos.ac.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991