The effect of carbamide on the composition of gas phase formed upon thermal destruction of graphite nitrate


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The composition of gas evolved upon thermal decomposition of individual and carbamidemodified graphite nitrates was determined. The addition of carbamide was shown to result in the 2—4-fold decrease in the content of nitrogen oxides and the 2—5-fold increase in the content of carbon monoxide. The content of nitrogen oxides in the gas phase decreased when the HNO3 : (NH2)2CO molar ratio was equal to 1 : (0.4—1). Combination of carbamide addition with catalytic afterburning provides the 5-fold decrease in the gas-phase amount of nitrogen oxides at the minimum CO content.

作者简介

A. Ivanov

Department of Chemistry, M. V. Lomonosov Moscow State University

Email: onshornikova@gmail.com
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991

S. Filimonov

Department of Chemistry, M. V. Lomonosov Moscow State University

Email: onshornikova@gmail.com
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991

O. Shornikova

Department of Chemistry, M. V. Lomonosov Moscow State University

编辑信件的主要联系方式.
Email: onshornikova@gmail.com
俄罗斯联邦, Build. 3, 1 Leninskie Gory, Moscow, 119991

A. Malakho

Institute of New Carbon Materials and Technologies

Email: onshornikova@gmail.com
俄罗斯联邦, Build. 11, 1 Leninskie Gory, Moscow, 119991


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