Potassium carbonate as a base for generation of carbanions from CH-acids in organic synthesis


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A reaction of CH-acids with electrophilic agent (Michael acceptors, alkyl and allyl halides, dihaloalkanes and -alkenes, etc.) in the presence of potassium carbonate constitutes a convenient method for the elongation of the carbon chain and provides a possibility to develop preparative methods for the preparation of both the linear and the cyclic structures.

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D. Khachatryan

Institute of Chemical Reactants and Ultrapure Compounds (IREA)

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Email: derenik-s@yandex.ru
俄罗斯联邦, 3 Bogorodskii val, Moscow, 107076

K. Matevosyan

D. I. Mendeleev University of Chemical Technology of Russia

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俄罗斯联邦, 9 Miusskaya pl., Moscow, 125047


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