Email this article Potassium carbonate as a base for generation of carbanions from CH-acids in organic synthesis
- Authors: Khachatryan D.S.1, Matevosyan K.R.2
-
Affiliations:
- Institute of Chemical Reactants and Ultrapure Compounds (IREA)
- D. I. Mendeleev University of Chemical Technology of Russia
- Issue: Vol 65, No 1 (2016)
- Pages: 14-28
- Section: Reviews
- URL: https://journals.rcsi.science/1066-5285/article/view/236805
- DOI: https://doi.org/10.1007/s11172-016-1260-z
- ID: 236805
Cite item
Open Access
Access granted
Subscription Access
Abstract
A reaction of CH-acids with electrophilic agent (Michael acceptors, alkyl and allyl halides, dihaloalkanes and -alkenes, etc.) in the presence of potassium carbonate constitutes a convenient method for the elongation of the carbon chain and provides a possibility to develop preparative methods for the preparation of both the linear and the cyclic structures.
About the authors
D. S. Khachatryan
Institute of Chemical Reactants and Ultrapure Compounds (IREA)
Author for correspondence.
Email: derenik-s@yandex.ru
Russian Federation, 3 Bogorodskii val, Moscow, 107076
K. R. Matevosyan
D. I. Mendeleev University of Chemical Technology of Russia
Email: derenik-s@yandex.ru
Russian Federation, 9 Miusskaya pl., Moscow, 125047
