N,N-Di(pyridin-2-yl)quinolin-6-amine: synthesis and coordination properties


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Аннотация

N,N-Di(pyridin-2-yl)quinolin-6-amine which is a new ditopic fluorescent ligand based on di(pyridin-2-yl)amine was synthesized and characterized. Using the methods of fluorescence and UV-vis spectroscopy, the complex formation of this ligand with the CoII, NiII, QuII, ZnII and PbII cations in acetonitrile was studied, the composition and the stability constants of the resulting complexes were determined. Their structure was studied by NMR using the zinc complex as an example.

Об авторах

A. Kharlamova

Department of Chemistry, M. V. Lomonosov Moscow State University

Email: antonabel@list.ru
Россия, 1-3 Leninskie Gory, Moscow, 119991

A. Abel

Department of Chemistry, M. V. Lomonosov Moscow State University

Автор, ответственный за переписку.
Email: antonabel@list.ru
Россия, 1-3 Leninskie Gory, Moscow, 119991

A. Averin

Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Email: antonabel@list.ru
Россия, 1-3 Leninskie Gory, Moscow, 119991; 31-4, Leninsky prosp., Moscow, 119991

I. Beletskaya

Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Email: antonabel@list.ru
Россия, 1-3 Leninskie Gory, Moscow, 119991; 31-4, Leninsky prosp., Moscow, 119991


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