N,N -Di(pyridin-2-yl)quinolin-6-amine: synthesis and coordination properties

A. D. Kharlamova; A. S. Abel; A. D. Averin; I. P. Beletskaya

doi:10.1007/s11172-019-2460-0

N,N-Di(pyridin-2-yl)quinolin-6-amine: synthesis and coordination properties

Authors: Kharlamova A.D.¹, Abel A.S.¹, Averin A.D.¹^,2, Beletskaya I.P.¹^,2
Affiliations:
1. Department of Chemistry, M. V. Lomonosov Moscow State University
2. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Issue: Vol 68, No 3 (2019)
Pages: 597-600
Section: Full Article
URL: https://journals.rcsi.science/1066-5285/article/view/243321
DOI: https://doi.org/10.1007/s11172-019-2460-0
ID: 243321

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Abstract
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Abstract

N,N-Di(pyridin-2-yl)quinolin-6-amine which is a new ditopic fluorescent ligand based on di(pyridin-2-yl)amine was synthesized and characterized. Using the methods of fluorescence and UV-vis spectroscopy, the complex formation of this ligand with the Co^II, Ni^II, Qu^II, Zn^II and Pb^II cations in acetonitrile was studied, the composition and the stability constants of the resulting complexes were determined. Their structure was studied by NMR using the zinc complex as an example.

About the authors

A. D. Kharlamova

Department of Chemistry, M. V. Lomonosov Moscow State University

Email: antonabel@list.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991

A. S. Abel

Department of Chemistry, M. V. Lomonosov Moscow State University

Author for correspondence.
Email: antonabel@list.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991

A. D. Averin

Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Email: antonabel@list.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991; 31-4, Leninsky prosp., Moscow, 119991

I. P. Beletskaya