N,N-Di(pyridin-2-yl)quinolin-6-amine: synthesis and coordination properties


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Abstract

N,N-Di(pyridin-2-yl)quinolin-6-amine which is a new ditopic fluorescent ligand based on di(pyridin-2-yl)amine was synthesized and characterized. Using the methods of fluorescence and UV-vis spectroscopy, the complex formation of this ligand with the CoII, NiII, QuII, ZnII and PbII cations in acetonitrile was studied, the composition and the stability constants of the resulting complexes were determined. Their structure was studied by NMR using the zinc complex as an example.

About the authors

A. D. Kharlamova

Department of Chemistry, M. V. Lomonosov Moscow State University

Email: antonabel@list.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991

A. S. Abel

Department of Chemistry, M. V. Lomonosov Moscow State University

Author for correspondence.
Email: antonabel@list.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991

A. D. Averin

Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Email: antonabel@list.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991; 31-4, Leninsky prosp., Moscow, 119991

I. P. Beletskaya

Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences

Email: antonabel@list.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991; 31-4, Leninsky prosp., Moscow, 119991

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