N,N-Di(pyridin-2-yl)quinolin-6-amine: synthesis and coordination properties
- Authors: Kharlamova A.D.1, Abel A.S.1, Averin A.D.1,2, Beletskaya I.P.1,2
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Affiliations:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
- Issue: Vol 68, No 3 (2019)
- Pages: 597-600
- Section: Full Article
- URL: https://journals.rcsi.science/1066-5285/article/view/243321
- DOI: https://doi.org/10.1007/s11172-019-2460-0
- ID: 243321
Cite item
Abstract
N,N-Di(pyridin-2-yl)quinolin-6-amine which is a new ditopic fluorescent ligand based on di(pyridin-2-yl)amine was synthesized and characterized. Using the methods of fluorescence and UV-vis spectroscopy, the complex formation of this ligand with the CoII, NiII, QuII, ZnII and PbII cations in acetonitrile was studied, the composition and the stability constants of the resulting complexes were determined. Their structure was studied by NMR using the zinc complex as an example.
About the authors
A. D. Kharlamova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: antonabel@list.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991
A. S. Abel
Department of Chemistry, M. V. Lomonosov Moscow State University
Author for correspondence.
Email: antonabel@list.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991
A. D. Averin
Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Email: antonabel@list.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991; 31-4, Leninsky prosp., Moscow, 119991
I. P. Beletskaya
Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences
Email: antonabel@list.ru
Russian Federation, 1-3 Leninskie Gory, Moscow, 119991; 31-4, Leninsky prosp., Moscow, 119991