Enviar artigo por via de e-mail Thermal cyclopropyl—allyl rearrangement of gem-chlorofluorocyclopropanes under gas-phase pyrolysis conditions. Formation of chlorofluoroalkenes and 2-fluorobuta-1,3-dienes
- Autores: Volchkov N.1, Lipkind M.1, Nefedov O.1
-
Afiliações:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Edição: Volume 68, Nº 7 (2019)
- Páginas: 1391-1401
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243428
- DOI: https://doi.org/10.1007/s11172-019-2567-3
- ID: 243428
Citar
Acesso aberto
Acesso está concedido
Somente assinantes
Resumo
The gas-phase pyrolysis of isomeric 2-chloro-2-fluoro-1-phenylcyclopropanes in a flow reactor at 250–430 °С gives 1-phenyl- and 3-phenyl-3-chloro-2-fluoropropenes. Under similar conditions, methyl-substituted gem-chlorofluorocyclopropanes undergo cyclopropyl—allyl isomerization accompanied by dehydrochlorination to form chlorofluoroalkenes and 2-fluoro-buta-1,3-dienes.
Sobre autores
N. Volchkov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Autor responsável pela correspondência
Email: volchkov@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991
M. Lipkind
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: volchkov@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991
O. Nefedov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: volchkov@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991
