Thermal cyclopropyl—allyl rearrangement of gem-chlorofluorocyclopropanes under gas-phase pyrolysis conditions. Formation of chlorofluoroalkenes and 2-fluorobuta-1,3-dienes
- 作者: Volchkov N.1, Lipkind M.1, Nefedov O.1
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隶属关系:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- 期: 卷 68, 编号 7 (2019)
- 页面: 1391-1401
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243428
- DOI: https://doi.org/10.1007/s11172-019-2567-3
- ID: 243428
如何引用文章
详细
The gas-phase pyrolysis of isomeric 2-chloro-2-fluoro-1-phenylcyclopropanes in a flow reactor at 250–430 °С gives 1-phenyl- and 3-phenyl-3-chloro-2-fluoropropenes. Under similar conditions, methyl-substituted gem-chlorofluorocyclopropanes undergo cyclopropyl—allyl isomerization accompanied by dehydrochlorination to form chlorofluoroalkenes and 2-fluoro-buta-1,3-dienes.
作者简介
N. Volchkov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: volchkov@ioc.ac.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991
M. Lipkind
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: volchkov@ioc.ac.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991
O. Nefedov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: volchkov@ioc.ac.ru
俄罗斯联邦, 47 Leninsky prosp., Moscow, 119991