Enviar artigo por via de e-mail Influence of molecular organization of an azido alcohol solution on the urethane formation kinetics
- Autores: Karpov S.V.1, Lodygina V.P.1, Malkov G.V.1, Badamshina E.R.1
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Afiliações:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Edição: Volume 65, Nº 10 (2016)
- Páginas: 2415-2420
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/239106
- DOI: https://doi.org/10.1007/s11172-016-1599-1
- ID: 239106
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Resumo
The quantitative data on the influence of molecular organization of CH2Cl2 solutions of diazidopropanol and its non-azide analog (isopropanol) and the concentrations of the alcohols and catalyst (dibutyltin dilaurinate) on the kinetics of urethane formation via the reaction with 1,6-hexamethylene diisocyanate were obtained. The series of reactivity were composed for various associates of hydroxyl groups of these alcohols in solutions in the catalytic and non-catalytic reactions.
Sobre autores
S. Karpov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Autor responsável pela correspondência
Email: svkarpov@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
V. Lodygina
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: svkarpov@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. Malkov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: svkarpov@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
E. Badamshina
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: svkarpov@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
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