Email this article Influence of molecular organization of an azido alcohol solution on the urethane formation kinetics
- Authors: Karpov S.V.1, Lodygina V.P.1, Malkov G.V.1, Badamshina E.R.1
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Affiliations:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Issue: Vol 65, No 10 (2016)
- Pages: 2415-2420
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/239106
- DOI: https://doi.org/10.1007/s11172-016-1599-1
- ID: 239106
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Abstract
The quantitative data on the influence of molecular organization of CH2Cl2 solutions of diazidopropanol and its non-azide analog (isopropanol) and the concentrations of the alcohols and catalyst (dibutyltin dilaurinate) on the kinetics of urethane formation via the reaction with 1,6-hexamethylene diisocyanate were obtained. The series of reactivity were composed for various associates of hydroxyl groups of these alcohols in solutions in the catalytic and non-catalytic reactions.
About the authors
S. V. Karpov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Author for correspondence.
Email: svkarpov@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
V. P. Lodygina
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: svkarpov@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
G. V. Malkov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: svkarpov@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
E. R. Badamshina
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: svkarpov@icp.ac.ru
Russian Federation, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
