Enviar artigo por via de e-mail Synthesis of new isoxazolidine (η5-cyclopentadienyl)manganese tricarbonyl complexes by 1,3-dipolar cycloaddition reaction
- Autores: Zarovkina N.1, Sazonova E.1, Artemov A.1, Fukin G.1,2
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Afiliações:
- N. I. Lobachevsky National Research State University of Nizhny Novgorod
- G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
- Edição: Volume 65, Nº 7 (2016)
- Páginas: 1790-1797
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238576
- DOI: https://doi.org/10.1007/s11172-016-1512-y
- ID: 238576
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Resumo
1,3-Dipolar cycloaddition reactions of nitrones of general formula R2CH=N(O)R1, where R1 = Me, But, Ph, R2 = Ph, Cp[Mn(CO)3] with styrene and vinyl-η5-(cyclopentadienyl) manganese tricarbonyl were studied. The products of these reactions, i.e., isoxazolidines, were isolated, purified, and identified. A high selectivity of the cycloaddition reactions involving both dipoles and dipolarophiles containing cyclopentadienylmanganese tricarbonyl group was demonstrated.
Sobre autores
N. Zarovkina
N. I. Lobachevsky National Research State University of Nizhny Novgorod
Autor responsável pela correspondência
Email: zarovkinan@mail.ru
Rússia, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950
E. Sazonova
N. I. Lobachevsky National Research State University of Nizhny Novgorod
Email: zarovkinan@mail.ru
Rússia, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950
A. Artemov
N. I. Lobachevsky National Research State University of Nizhny Novgorod
Email: zarovkinan@mail.ru
Rússia, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950
G. Fukin
N. I. Lobachevsky National Research State University of Nizhny Novgorod; G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Email: zarovkinan@mail.ru
Rússia, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950; 49 ul. Tropinina, Nizhny Novgorod, 603950
