Email this article Synthesis of new isoxazolidine (η5-cyclopentadienyl)manganese tricarbonyl complexes by 1,3-dipolar cycloaddition reaction
- Authors: Zarovkina N.Y.1, Sazonova E.V.1, Artemov A.N.1, Fukin G.K.1,2
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Affiliations:
- N. I. Lobachevsky National Research State University of Nizhny Novgorod
- G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
- Issue: Vol 65, No 7 (2016)
- Pages: 1790-1797
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238576
- DOI: https://doi.org/10.1007/s11172-016-1512-y
- ID: 238576
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Abstract
1,3-Dipolar cycloaddition reactions of nitrones of general formula R2CH=N(O)R1, where R1 = Me, But, Ph, R2 = Ph, Cp[Mn(CO)3] with styrene and vinyl-η5-(cyclopentadienyl) manganese tricarbonyl were studied. The products of these reactions, i.e., isoxazolidines, were isolated, purified, and identified. A high selectivity of the cycloaddition reactions involving both dipoles and dipolarophiles containing cyclopentadienylmanganese tricarbonyl group was demonstrated.
About the authors
N. Yu. Zarovkina
N. I. Lobachevsky National Research State University of Nizhny Novgorod
Author for correspondence.
Email: zarovkinan@mail.ru
Russian Federation, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950
E. V. Sazonova
N. I. Lobachevsky National Research State University of Nizhny Novgorod
Email: zarovkinan@mail.ru
Russian Federation, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950
A. N. Artemov
N. I. Lobachevsky National Research State University of Nizhny Novgorod
Email: zarovkinan@mail.ru
Russian Federation, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950
G. K. Fukin
N. I. Lobachevsky National Research State University of Nizhny Novgorod; G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Email: zarovkinan@mail.ru
Russian Federation, 5 korp., 23 prosp. Gagarina, Nizhny Novgorod, 603950; 49 ul. Tropinina, Nizhny Novgorod, 603950
