Mechanochemical synthesis of platinum(IV) complexes with N-heterocyclic carbenes
- Авторлар: Chikunov I.1, Ranny G.1, Astakhov A.1, Tafeenko V.2, Chernyshev V.1
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Мекемелер:
- Platov South-Russian State Polytechnic University (NPI)
- Lomonosov Moscow State University
- Шығарылым: Том 67, № 11 (2018)
- Беттер: 2003-2009
- Бөлім: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243160
- DOI: https://doi.org/10.1007/s11172-018-2321-2
- ID: 243160
Дәйексөз келтіру
Аннотация
A new method for the synthesis of complexes PtIV(NHC)X4L (NHC is N-heterocyclic carbene of imidazole or benzimidazole series; X = Cl, Br; L is N-coordinated pyridine or NHC) based on mechanochemical oxidation of complexes PtII(NHC)X2L with dichloroiodobenzene (PhICl2) or pyridinium hydrobromide perbromide (PyHBr3) was proposed. Mechanochemical activation led to reduction in the synthesis time and increase in the selectivity of halogenation and yields of the target PtIV complexes (74–98%) as compared to the reaction in solutions.
Авторлар туралы
I. Chikunov
Platov South-Russian State Polytechnic University (NPI)
Email: chern13@yandex.ru
Ресей, 132 ul. Prosveshcheniya, Novocherkassk, 346428
G. Ranny
Platov South-Russian State Polytechnic University (NPI)
Email: chern13@yandex.ru
Ресей, 132 ul. Prosveshcheniya, Novocherkassk, 346428
A. Astakhov
Platov South-Russian State Polytechnic University (NPI)
Email: chern13@yandex.ru
Ресей, 132 ul. Prosveshcheniya, Novocherkassk, 346428
V. Tafeenko
Lomonosov Moscow State University
Email: chern13@yandex.ru
Ресей, 1 Leninskie Gory, Moscow, 119991
V. Chernyshev
Platov South-Russian State Polytechnic University (NPI)
Хат алмасуға жауапты Автор.
Email: chern13@yandex.ru
Ресей, 132 ul. Prosveshcheniya, Novocherkassk, 346428