Mechanochemical synthesis of platinum(IV) complexes with N-heterocyclic carbenes
- 作者: Chikunov I.1, Ranny G.1, Astakhov A.1, Tafeenko V.2, Chernyshev V.1
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隶属关系:
- Platov South-Russian State Polytechnic University (NPI)
- Lomonosov Moscow State University
- 期: 卷 67, 编号 11 (2018)
- 页面: 2003-2009
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243160
- DOI: https://doi.org/10.1007/s11172-018-2321-2
- ID: 243160
如何引用文章
详细
A new method for the synthesis of complexes PtIV(NHC)X4L (NHC is N-heterocyclic carbene of imidazole or benzimidazole series; X = Cl, Br; L is N-coordinated pyridine or NHC) based on mechanochemical oxidation of complexes PtII(NHC)X2L with dichloroiodobenzene (PhICl2) or pyridinium hydrobromide perbromide (PyHBr3) was proposed. Mechanochemical activation led to reduction in the synthesis time and increase in the selectivity of halogenation and yields of the target PtIV complexes (74–98%) as compared to the reaction in solutions.
作者简介
I. Chikunov
Platov South-Russian State Polytechnic University (NPI)
Email: chern13@yandex.ru
俄罗斯联邦, 132 ul. Prosveshcheniya, Novocherkassk, 346428
G. Ranny
Platov South-Russian State Polytechnic University (NPI)
Email: chern13@yandex.ru
俄罗斯联邦, 132 ul. Prosveshcheniya, Novocherkassk, 346428
A. Astakhov
Platov South-Russian State Polytechnic University (NPI)
Email: chern13@yandex.ru
俄罗斯联邦, 132 ul. Prosveshcheniya, Novocherkassk, 346428
V. Tafeenko
Lomonosov Moscow State University
Email: chern13@yandex.ru
俄罗斯联邦, 1 Leninskie Gory, Moscow, 119991
V. Chernyshev
Platov South-Russian State Polytechnic University (NPI)
编辑信件的主要联系方式.
Email: chern13@yandex.ru
俄罗斯联邦, 132 ul. Prosveshcheniya, Novocherkassk, 346428