Kinetics and mechanism of radiation telomerization of tetrafluoroethylene in hexafluoropropan-2-ol and trifluoroethanol

G. A. Kichigina; P. P. Kushch; D. P. Kiryukhin; S. I. Kuzina; A. I. Mikhailov

doi:10.1007/s11172-017-1756-1

Kinetics and mechanism of radiation telomerization of tetrafluoroethylene in hexafluoropropan-2-ol and trifluoroethanol

Авторлар: Kichigina G.¹, Kushch P.¹, Kiryukhin D.¹, Kuzina S.¹, Mikhailov A.¹
Мекемелер:
1. Institute of Problems of Chemical Physics, Russian Academy of Sciences
Шығарылым: Том 66, № 3 (2017)
Беттер: 468-473
Бөлім: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/240163
DOI: https://doi.org/10.1007/s11172-017-1756-1
ID: 240163

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат
Рұқсат жабық

Рұқсат берілді
Рұқсат жабық

Тек жазылушылар үшін

Аннотация
Авторлар туралы
Әдебиет тізімі
Статистика

Аннотация

The kinetics of radiation telomerization of tetrafluoroethylene (TFE) in trifluoroethanol and hexafluoropropan-2-ol (HFIP) has been investigated by method of kinetic calorimetry. The nature of active centers initiating the process of telomerization of tetrafluoroethylene in hexafluoroisopropanol in the temperature range of 77—300 K was investigated by ESR spectroscopy. The molecular structure and properties of the obtained telomeres were studied by IR spectroscopy and TGA.