Kinetics and mechanism of radiation telomerization of tetrafluoroethylene in hexafluoropropan-2-ol and trifluoroethanol
- Autores: Kichigina G.1, Kushch P.1, Kiryukhin D.1, Kuzina S.1, Mikhailov A.1
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Afiliações:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Edição: Volume 66, Nº 3 (2017)
- Páginas: 468-473
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240163
- DOI: https://doi.org/10.1007/s11172-017-1756-1
- ID: 240163
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Resumo
The kinetics of radiation telomerization of tetrafluoroethylene (TFE) in trifluoroethanol and hexafluoropropan-2-ol (HFIP) has been investigated by method of kinetic calorimetry. The nature of active centers initiating the process of telomerization of tetrafluoroethylene in hexafluoroisopropanol in the temperature range of 77—300 K was investigated by ESR spectroscopy. The molecular structure and properties of the obtained telomeres were studied by IR spectroscopy and TGA.
Sobre autores
G. Kichigina
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Autor responsável pela correspondência
Email: kga@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
P. Kushch
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: kga@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
D. Kiryukhin
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: kga@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
S. Kuzina
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: kga@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432
A. Mikhailov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: kga@icp.ac.ru
Rússia, 1 prosp. Akad. Semenova, Chernogolovka, Moscow Region, 142432