Отправить статью по E-mail Reactivity of phosphine oxide H3PO in the reactions with ketones
- Авторы: Gorbachuk E.V.1,2, Badeeva E.K.1, Babaev V.M.1, Rizvanov I.K.1, Zinnatullin R.G.1,2, Pavlov P.O.1,2, Khayarov K.R.2, Yakhvarov D.G.1,2
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Учреждения:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Kazan Federal University
- Выпуск: Том 65, № 5 (2016)
- Страницы: 1289-1294
- Раздел: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238152
- DOI: https://doi.org/10.1007/s11172-016-1450-8
- ID: 238152
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Аннотация
The reactivity of the electrochemically generated phosphine oxide H3PO towards ketones (acetone, ethyl methyl ketone, methyl n-propyl ketone, and tert-butyl methyl ketone) has been studied. It was found that this reaction led to the formation of mono- and bis(hydroxyalkyl)phosphine oxides of the formulas RRĆ(OH)P(O)H2 and [RRĆ(OH)]2P(O)H (R = Me; R´ = Me, Et, Pr) and represents the first example of the P—C bond formation involving the intermediate H3PO.
Об авторах
E. Gorbachuk
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Email: yakhvar@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
E. Badeeva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yakhvar@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
V. Babaev
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yakhvar@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
I. Rizvanov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yakhvar@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088
R. Zinnatullin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Email: yakhvar@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
P. Pavlov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Email: yakhvar@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
Kh. Khayarov
Kazan Federal University
Email: yakhvar@iopc.ru
Россия, 18 ul. Kremlyovskaya, Kazan, 420008
D. Yakhvarov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Автор, ответственный за переписку.
Email: yakhvar@iopc.ru
Россия, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
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