Мақаланы E-mail арқылы жіберу Reactivity of phosphine oxide H3PO in the reactions with ketones
- Авторлар: Gorbachuk E.1,2, Badeeva E.1, Babaev V.1, Rizvanov I.1, Zinnatullin R.1,2, Pavlov P.1,2, Khayarov K.2, Yakhvarov D.1,2
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Мекемелер:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Kazan Federal University
- Шығарылым: Том 65, № 5 (2016)
- Беттер: 1289-1294
- Бөлім: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238152
- DOI: https://doi.org/10.1007/s11172-016-1450-8
- ID: 238152
Дәйексөз келтіру
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Рұқсат берілді
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Аннотация
The reactivity of the electrochemically generated phosphine oxide H3PO towards ketones (acetone, ethyl methyl ketone, methyl n-propyl ketone, and tert-butyl methyl ketone) has been studied. It was found that this reaction led to the formation of mono- and bis(hydroxyalkyl)phosphine oxides of the formulas RRĆ(OH)P(O)H2 and [RRĆ(OH)]2P(O)H (R = Me; R´ = Me, Et, Pr) and represents the first example of the P—C bond formation involving the intermediate H3PO.
Авторлар туралы
E. Gorbachuk
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Email: yakhvar@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
E. Badeeva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yakhvar@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088
V. Babaev
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yakhvar@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088
I. Rizvanov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yakhvar@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088
R. Zinnatullin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Email: yakhvar@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
P. Pavlov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Email: yakhvar@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
Kh. Khayarov
Kazan Federal University
Email: yakhvar@iopc.ru
Ресей, 18 ul. Kremlyovskaya, Kazan, 420008
D. Yakhvarov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Хат алмасуға жауапты Автор.
Email: yakhvar@iopc.ru
Ресей, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
