电邮这篇文章 Reactivity of phosphine oxide H3PO in the reactions with ketones
- 作者: Gorbachuk E.1,2, Badeeva E.1, Babaev V.1, Rizvanov I.1, Zinnatullin R.1,2, Pavlov P.1,2, Khayarov K.2, Yakhvarov D.1,2
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隶属关系:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Kazan Federal University
- 期: 卷 65, 编号 5 (2016)
- 页面: 1289-1294
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/238152
- DOI: https://doi.org/10.1007/s11172-016-1450-8
- ID: 238152
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详细
The reactivity of the electrochemically generated phosphine oxide H3PO towards ketones (acetone, ethyl methyl ketone, methyl n-propyl ketone, and tert-butyl methyl ketone) has been studied. It was found that this reaction led to the formation of mono- and bis(hydroxyalkyl)phosphine oxides of the formulas RRĆ(OH)P(O)H2 and [RRĆ(OH)]2P(O)H (R = Me; R´ = Me, Et, Pr) and represents the first example of the P—C bond formation involving the intermediate H3PO.
作者简介
E. Gorbachuk
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Email: yakhvar@iopc.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
E. Badeeva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yakhvar@iopc.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088
V. Babaev
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yakhvar@iopc.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088
I. Rizvanov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yakhvar@iopc.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088
R. Zinnatullin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Email: yakhvar@iopc.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
P. Pavlov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
Email: yakhvar@iopc.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
Kh. Khayarov
Kazan Federal University
Email: yakhvar@iopc.ru
俄罗斯联邦, 18 ul. Kremlyovskaya, Kazan, 420008
D. Yakhvarov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences; Kazan Federal University
编辑信件的主要联系方式.
Email: yakhvar@iopc.ru
俄罗斯联邦, 8 ul. Akad. Arbuzova, Kazan, 420088; 18 ul. Kremlyovskaya, Kazan, 420008
