Email this article Comparative reactivity of hydroxyketones and their derivatives in the reactions with N,S-nucleophiles
- Authors: Pulatov E.K.1, Isobaev M.D.1, Mavlonov B.G.1, Abdullaev T.K.1
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Affiliations:
- V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Republic of Tajikistan
- Issue: Vol 67, No 6 (2018)
- Pages: 1106-1109
- Section: Brief Communications
- URL: https://journals.rcsi.science/1066-5285/article/view/242654
- DOI: https://doi.org/10.1007/s11172-018-2188-2
- ID: 242654
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Abstract
The reactions of thiosemicarbazide (TSC), thiocarbohydrazide, and hydrazine thiocarbamate with oxyketones, haloketones, and derivatives of acetylenic alcohols were studied. Thiadiazines bearing exocyclic thio and hydrazo groups were synthesized. Acetylenic alcohols react with TSC to give the corresponding thiazolidines. The reactions of halo derivatives of acetylenic alcohols with TSC are complicated by side reactions.
About the authors
E. Kh. Pulatov
V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Republic of Tajikistan
Email: coordin@yandex.ru
Tajikistan, 299/2 ul. Aini, 734063, Dushanbe
M. D. Isobaev
V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Republic of Tajikistan
Author for correspondence.
Email: coordin@yandex.ru
Tajikistan, 299/2 ul. Aini, 734063, Dushanbe
B. G. Mavlonov
V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Republic of Tajikistan
Email: coordin@yandex.ru
Tajikistan, 299/2 ul. Aini, 734063, Dushanbe
T. Kh. Abdullaev
V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Republic of Tajikistan
Email: coordin@yandex.ru
Tajikistan, 299/2 ul. Aini, 734063, Dushanbe
