Selective synthesis of cyclic triperoxides from 1,1′-dihydroperoxydi(cycloalkyl)peroxides and acetals using SnCl4


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A method for the synthesis of 1,2,4,5,7,8-hexaoxonanes by the reaction of 1,1′-dihydroperoxydi(cycloalkyl)peroxides with acetals using SnCl4 has been developed. For the first time, it was shown that SnCl4 can serve as an effective reagent for the synthesis of cyclic organic peroxides. The proposed method allows obtaining 9-membered cyclic triperoxides selectively and in the yields of up to 90% based on the isolated product.

Sobre autores

P. Radulov

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences; All-Russia Research Institute for Phytopathology

Email: terentev@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991; 5 ul. Institut, Bolshie Vyazyomy, Odintsovo District, Moscow Region, 143050

Yu. Belyakova

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Email: terentev@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991

A. Demina

M. V. Lomonosov Moscow State University

Email: terentev@ioc.ac.ru
Rússia, 1-3 Leninskiye Gory, Moscow, 119991

G. Nikishin

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Email: terentev@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991

I. Yaremenko

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences; All-Russia Research Institute for Phytopathology; D. I. Mendeleev University of Chemical Technology of Russia

Email: terentev@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991; 5 ul. Institut, Bolshie Vyazyomy, Odintsovo District, Moscow Region, 143050; 9 Miusskaya pl., Moscow, 125047

A. Terent’ev

N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences; All-Russia Research Institute for Phytopathology; D. I. Mendeleev University of Chemical Technology of Russia

Autor responsável pela correspondência
Email: terentev@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991; 5 ul. Institut, Bolshie Vyazyomy, Odintsovo District, Moscow Region, 143050; 9 Miusskaya pl., Moscow, 125047

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