Chiral cryptands possessing fragments of (S)-2,2′-diamino-1,1′-binaphtalene and diaza-crown ethers
- Authors: Gusev D.I.1, Averin A.D.1,2, Maloshitskaya O.A.1, Beletskaya I.P.1,2, Grigorova O.K.1
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Affiliations:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Issue: Vol 68, No 4 (2019)
- Pages: 848-854
- Section: Full Article
- URL: https://journals.rcsi.science/1066-5285/article/view/243356
- DOI: https://doi.org/10.1007/s11172-019-2495-2
- ID: 243356
Cite item
Abstract
A series of optically active macrobicyclic cryptands were obtained by the Pd0-catalyzed amination reaction between (S)-2,2′-diamino-1,1′-binaphtalene (BINAM) and N,N′-bis-(bromobenzyl) derivatives of diaza-crown ethers. The dependence of yields of the macrobicyclic products on the structure of the diaza-crown ether derivatives was demonstrated. A comprehensive study of the effects of a number of optically active amino alcohols on the fluorescence spectra of the prepared compounds was carried out.
About the authors
D. I. Gusev
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: alexaveron@yandex.ru
Russian Federation, 1/3 Leninskye Gory, Moscow, 119991
A. D. Averin
Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Author for correspondence.
Email: alexaveron@yandex.ru
Russian Federation, 1/3 Leninskye Gory, Moscow, 119991; 31/4 Leninsky prosp., Moscow, 119991
O. A. Maloshitskaya
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: alexaveron@yandex.ru
Russian Federation, 1/3 Leninskye Gory, Moscow, 119991
I. P. Beletskaya
Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: alexaveron@yandex.ru
Russian Federation, 1/3 Leninskye Gory, Moscow, 119991; 31/4 Leninsky prosp., Moscow, 119991
O. K. Grigorova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: alexaveron@yandex.ru
Russian Federation, 1/3 Leninskye Gory, Moscow, 119991