Chiral cryptands possessing fragments of (S)-2,2′-diamino-1,1′-binaphtalene and diaza-crown ethers
- 作者: Gusev D.1, Averin A.1,2, Maloshitskaya O.1, Beletskaya I.1,2, Grigorova O.1
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隶属关系:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- 期: 卷 68, 编号 4 (2019)
- 页面: 848-854
- 栏目: Full Article
- URL: https://journals.rcsi.science/1066-5285/article/view/243356
- DOI: https://doi.org/10.1007/s11172-019-2495-2
- ID: 243356
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详细
A series of optically active macrobicyclic cryptands were obtained by the Pd0-catalyzed amination reaction between (S)-2,2′-diamino-1,1′-binaphtalene (BINAM) and N,N′-bis-(bromobenzyl) derivatives of diaza-crown ethers. The dependence of yields of the macrobicyclic products on the structure of the diaza-crown ether derivatives was demonstrated. A comprehensive study of the effects of a number of optically active amino alcohols on the fluorescence spectra of the prepared compounds was carried out.
作者简介
D. Gusev
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: alexaveron@yandex.ru
俄罗斯联邦, 1/3 Leninskye Gory, Moscow, 119991
A. Averin
Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: alexaveron@yandex.ru
俄罗斯联邦, 1/3 Leninskye Gory, Moscow, 119991; 31/4 Leninsky prosp., Moscow, 119991
O. Maloshitskaya
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: alexaveron@yandex.ru
俄罗斯联邦, 1/3 Leninskye Gory, Moscow, 119991
I. Beletskaya
Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: alexaveron@yandex.ru
俄罗斯联邦, 1/3 Leninskye Gory, Moscow, 119991; 31/4 Leninsky prosp., Moscow, 119991
O. Grigorova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: alexaveron@yandex.ru
俄罗斯联邦, 1/3 Leninskye Gory, Moscow, 119991