Email this article One-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re4(µ3-Q)4}(CN)12]4− (Q = S, Se, Te) using ReI3
- Authors: Pronin A.S.1, Smolentsev A.I.1,2, Mironov Y.V.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Issue: Vol 68, No 4 (2019)
- Pages: 777-781
- Section: Full Article
- URL: https://journals.rcsi.science/1066-5285/article/view/243346
- DOI: https://doi.org/10.1007/s11172-019-2485-4
- ID: 243346
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Abstract
A new method is proposed for the one-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re4(µ3-Q)4}(CN)12]4− (Q = S, Se, Te) using rhenium(iii) iodide as the starting compound. A cluster complex of the composition K4[{Re4S4}(CN)12]•H2O was synthesized for the first time and characterized by X-ray diffraction.
About the authors
A. S. Pronin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: yuri@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090
A. I. Smolentsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: yuri@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 1 ul. Pirogova, Novosibirsk, 630090
Y. V. Mironov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Author for correspondence.
Email: yuri@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 1 ul. Pirogova, Novosibirsk, 630090
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