One-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re43-Q)4}(CN)12]4− (Q = S, Se, Te) using ReI3


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A new method is proposed for the one-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re43-Q)4}(CN)12]4− (Q = S, Se, Te) using rhenium(iii) iodide as the starting compound. A cluster complex of the composition K4[{Re4S4}(CN)12]•H2O was synthesized for the first time and characterized by X-ray diffraction.

作者简介

A. Pronin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: yuri@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090

A. Smolentsev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Email: yuri@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 1 ul. Pirogova, Novosibirsk, 630090

Y. Mironov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

编辑信件的主要联系方式.
Email: yuri@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 1 ul. Pirogova, Novosibirsk, 630090

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