Synthesis and crystal structure of the coordination polymer [{Li(H2O)3}2(C36H36N24O12)]Cl2•6H2O


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The coordination polymer of the composition [{Li(H2O)3}2(C36H36N24O12)]Cl2•6H2O (1) was synthesized by heating an aqueous solution of lithium chloride and cucurbit[6]uril (CB[6]). According to single-crystal X-ray diffraction data, solvated lithium cations in compound 1 form coordination bonds with oxygen atoms of CB[6] molecules. Compound 1 was characterized by X-ray diffraction, IR spectroscopy, thermogravimetric and elemental analysis. Luminescence spectra of the new compound were measured.

作者简介

E. Kovalenko

A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: cluster@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090

D. Samsonenko

A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Email: cluster@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090

V. Fedin

A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

编辑信件的主要联系方式.
Email: cluster@niic.nsc.ru
俄罗斯联邦, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090

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