Email this article Synthesis and crystal structure of the coordination polymer [{Li(H2O)3}2(C36H36N24O12)]Cl2•6H2O
- Authors: Kovalenko E.A.1, Samsonenko D.G.1,2, Fedin V.P.1,2
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Affiliations:
- A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Novosibirsk State University
- Issue: Vol 67, No 1 (2018)
- Pages: 127-130
- Section: Article
- URL: https://journals.rcsi.science/1066-5285/article/view/241972
- DOI: https://doi.org/10.1007/s11172-018-2047-1
- ID: 241972
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Abstract
The coordination polymer of the composition [{Li(H2O)3}2(C36H36N24O12)]Cl2•6H2O (1) was synthesized by heating an aqueous solution of lithium chloride and cucurbit[6]uril (CB[6]). According to single-crystal X-ray diffraction data, solvated lithium cations in compound 1 form coordination bonds with oxygen atoms of CB[6] molecules. Compound 1 was characterized by X-ray diffraction, IR spectroscopy, thermogravimetric and elemental analysis. Luminescence spectra of the new compound were measured.
About the authors
E. A. Kovalenko
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090
D. G. Samsonenko
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
V. P. Fedin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University
Author for correspondence.
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
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