Synthesis and crystal structure of the coordination polymer [{Li(H2O)3}2(C36H36N24O12)]Cl2•6H2O


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Аннотация

The coordination polymer of the composition [{Li(H2O)3}2(C36H36N24O12)]Cl2•6H2O (1) was synthesized by heating an aqueous solution of lithium chloride and cucurbit[6]uril (CB[6]). According to single-crystal X-ray diffraction data, solvated lithium cations in compound 1 form coordination bonds with oxygen atoms of CB[6] molecules. Compound 1 was characterized by X-ray diffraction, IR spectroscopy, thermogravimetric and elemental analysis. Luminescence spectra of the new compound were measured.

Авторлар туралы

E. Kovalenko

A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences

Email: cluster@niic.nsc.ru
Ресей, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090

D. Samsonenko

A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Email: cluster@niic.nsc.ru
Ресей, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090

V. Fedin

A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Novosibirsk State University

Хат алмасуға жауапты Автор.
Email: cluster@niic.nsc.ru
Ресей, 3 prosp. Akad. Lavrentieva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090

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