Email this article Optically active derivatives of terephthalic acid: synthesis and crystal structures
- Authors: Veselovsky V.V.1, Lozanova A.V.1, Isaeva V.I.1, Lobova A.A.2, Chernyshev V.V.2,3
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Affiliations:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- Department of Chemistry, M. V. Lomonosov Moscow State University
- A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Issue: Vol 66, No 9 (2017)
- Pages: 1589-1596
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/241203
- DOI: https://doi.org/10.1007/s11172-017-1928-z
- ID: 241203
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Abstract
New optically active derivatives of terephthalic acid, which are of interest as precursors of chiral metal-organic frameworks (MOFs), were synthesized starting from available dimethyl 2-aminoterephthalate, N-Boc-l-alanine, and N-Boc-l-proline. The crystal structures of three samples were determined by powder X-ray diffraction. In all three structures, the acid molecules exist as zwitterions.
About the authors
V. V. Veselovsky
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: ves@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
A. V. Lozanova
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vladimir@struct.chem.msu.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
V. I. Isaeva
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vladimir@struct.chem.msu.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
A. A. Lobova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: vladimir@struct.chem.msu.ru
Russian Federation, 1 Leninskie Gory, Moscow, 119899
V. V. Chernyshev
Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Author for correspondence.
Email: vladimir@struct.chem.msu.ru
Russian Federation, 1 Leninskie Gory, Moscow, 119899; 31 Leninsky prosp., Moscow, 119071
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