Optically active derivatives of terephthalic acid: synthesis and crystal structures


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Resumo

New optically active derivatives of terephthalic acid, which are of interest as precursors of chiral metal-organic frameworks (MOFs), were synthesized starting from available dimethyl 2-aminoterephthalate, N-Boc-l-alanine, and N-Boc-l-proline. The crystal structures of three samples were determined by powder X-ray diffraction. In all three structures, the acid molecules exist as zwitterions.

Sobre autores

V. Veselovsky

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: ves@ioc.ac.ru
Rússia, 47 Leninsky prosp., Moscow, 119991

A. Lozanova

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: vladimir@struct.chem.msu.ru
Rússia, 47 Leninsky prosp., Moscow, 119991

V. Isaeva

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: vladimir@struct.chem.msu.ru
Rússia, 47 Leninsky prosp., Moscow, 119991

A. Lobova

Department of Chemistry, M. V. Lomonosov Moscow State University

Email: vladimir@struct.chem.msu.ru
Rússia, 1 Leninskie Gory, Moscow, 119899

V. Chernyshev

Department of Chemistry, M. V. Lomonosov Moscow State University; A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: vladimir@struct.chem.msu.ru
Rússia, 1 Leninskie Gory, Moscow, 119899; 31 Leninsky prosp., Moscow, 119071

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