Email this article A comparative study of the reactions of fluorinated oxi- and thiiranes with acyl chlorides
- Authors: Nalet´ko S.A.1, Pervova M.G.1, Kodess M.I.1, Toporova M.S.1, Gorbunova T.I.1, Zapevalov A.Y.1, Saloutin V.I.1
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Affiliations:
- I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
- Issue: Vol 66, No 6 (2017)
- Pages: 1011-1017
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/240716
- DOI: https://doi.org/10.1007/s11172-017-1848-y
- ID: 240716
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Abstract
The CoCl2-catalyzed reactions of fluorinated 1,2-oxi- and thiiranes with acyl chlorides were studied. It was found that a regioselective heterocycle opening reaction resulted in two isomers having normal and abnormal structure in a ratio predetermined by the substituents in both the starting heterocycles and acyl chlorides.
About the authors
S. A. Nalet´ko
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Author for correspondence.
Email: naletko@ios.uran.ru
Russian Federation, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990
M. G. Pervova
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: naletko@ios.uran.ru
Russian Federation, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990
M. I. Kodess
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: naletko@ios.uran.ru
Russian Federation, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990
M. S. Toporova
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: naletko@ios.uran.ru
Russian Federation, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990
T. I. Gorbunova
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: naletko@ios.uran.ru
Russian Federation, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990
A. Ya. Zapevalov
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: naletko@ios.uran.ru
Russian Federation, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990
V. I. Saloutin
I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
Email: naletko@ios.uran.ru
Russian Federation, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990
