A comparative study of the reactions of fluorinated oxi- and thiiranes with acyl chlorides


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The CoCl2-catalyzed reactions of fluorinated 1,2-oxi- and thiiranes with acyl chlorides were studied. It was found that a regioselective heterocycle opening reaction resulted in two isomers having normal and abnormal structure in a ratio predetermined by the substituents in both the starting heterocycles and acyl chlorides.

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S. Nalet´ko

I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: naletko@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990

M. Pervova

I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Email: naletko@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990

M. Kodess

I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Email: naletko@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990

M. Toporova

I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Email: naletko@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990

T. Gorbunova

I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Email: naletko@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990

A. Zapevalov

I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Email: naletko@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990

V. Saloutin

I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

Email: naletko@ios.uran.ru
俄罗斯联邦, 22/20 ul. S. Kovalevskoy/Akademicheskaya, Ekaterinburg, 620990


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