Investigation of the reaction between phosphoenolpyruvic acid and thiosulfate-nitrosyl iron complex


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Abstract

Reaction between the nitric oxide donor, tetranitrosyl iron complex with thiosulfate ligand (TNIC), and phosphoenolpyruvic acid (PEP) was studied. Formation of products of the reaction between PEP and TNIC was confirmed by UV-, IR-spectroscopy, and mass spectrometry methods. Also, ions with mass numbers m/z 318 and m/z 256 were identi-fied among the reaction products, belonging to the compounds [O3S2—Fe—PEP]2– and [S—Fe—PEP]2–, respectively.

About the authors

A. A. Zanina

Department of Fundamental Physical and Chemical Engineering, M. V. Lomonosov Moscow State University

Email: easar@icp.ac.ru
Russian Federation, Bld. 51, 1 Leninskie Gory, Moscow, 119991

E. A. Saratovskikh

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Author for correspondence.
Email: easar@icp.ac.ru
Russian Federation, 1 prosp. Acad. Semenova, Chernogolovka, Moscow region, 142432

V. M. Martynenko

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: easar@icp.ac.ru
Russian Federation, 1 prosp. Acad. Semenova, Chernogolovka, Moscow region, 142432

B. L. Psikha

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: easar@icp.ac.ru
Russian Federation, 1 prosp. Acad. Semenova, Chernogolovka, Moscow region, 142432

N. A. Sanina

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: easar@icp.ac.ru
Russian Federation, 1 prosp. Acad. Semenova, Chernogolovka, Moscow region, 142432


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