Investigation of the reaction between phosphoenolpyruvic acid and thiosulfate-nitrosyl iron complex


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Аннотация

Reaction between the nitric oxide donor, tetranitrosyl iron complex with thiosulfate ligand (TNIC), and phosphoenolpyruvic acid (PEP) was studied. Formation of products of the reaction between PEP and TNIC was confirmed by UV-, IR-spectroscopy, and mass spectrometry methods. Also, ions with mass numbers m/z 318 and m/z 256 were identi-fied among the reaction products, belonging to the compounds [O3S2—Fe—PEP]2– and [S—Fe—PEP]2–, respectively.

Об авторах

A. Zanina

Department of Fundamental Physical and Chemical Engineering, M. V. Lomonosov Moscow State University

Email: easar@icp.ac.ru
Россия, Bld. 51, 1 Leninskie Gory, Moscow, 119991

E. Saratovskikh

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Автор, ответственный за переписку.
Email: easar@icp.ac.ru
Россия, 1 prosp. Acad. Semenova, Chernogolovka, Moscow region, 142432

V. Martynenko

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: easar@icp.ac.ru
Россия, 1 prosp. Acad. Semenova, Chernogolovka, Moscow region, 142432

B. Psikha

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: easar@icp.ac.ru
Россия, 1 prosp. Acad. Semenova, Chernogolovka, Moscow region, 142432

N. Sanina

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: easar@icp.ac.ru
Россия, 1 prosp. Acad. Semenova, Chernogolovka, Moscow region, 142432


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